Yes. As long as you've enabled Master Password Reset and added two Windows Hello factors (fingerprint and face) to your profile, you can reset your Master Password without a problem.
What if I can't use Windows Hello?
Don't worry, there's a solution. As long as you have Chrome, Firefox, or Internet Explorer installed on your Windows 10 PC, you can enable Master Password Reset in your profile. Here's how:
1) Sign in to your True Key desktop app.
2) Under the Settings Wheel, go to Profile Preferences
3) Scroll down to the bottom of the page until you see Disable Master Password Reset, and click on Enabled.
Make sure to add additional factors to your profile to help the True Key app verify it's you in the event that your forget your Master Password.